Your distribution network operator is not your electricity supplier. It is the company that owns and maintains the cables in your street, and it is determined by geography rather than by who you pay. If you do not know which one covers you, the Energy Networks Association publishes a postcode lookup.
Most operators provide an online form. In broad terms you will need the address and MPAN, your contact details, the manufacturer and model of the device, its declared output, and the commissioning date. Because compliant devices are on the ENA Connect Direct register, the device details can usually be picked from a list rather than typed.
It typically takes ten to fifteen minutes and gives you an instant acknowledgement. Keep that acknowledgement — it is the only evidence you have that the obligation was met, and it is the sort of thing a purchaser’s solicitor or a managing agent may eventually ask for.
The documentation supplied with the device must include a QR code directing you to the relevant guidance and registration process, so the easiest route is usually the one printed in the manual.