Personal Protective Equipment (PPE) is the last line of defence in the hierarchy of control. It does not eliminate or reduce the hazard itself — it protects the individual from the consequences of exposure to a hazard that has not been fully controlled by other means. For electricians, this means PPE protects you when safe isolation, lock off procedures, engineered barriers, and safe systems of work are either not possible or have failed.
The hierarchy of control, as set out in the Management of Health and Safety at Work Regulations 1999, is: eliminate, substitute, engineer, administrate, then PPE. You should always work through this hierarchy before relying on PPE. For example, the primary control for electric shock is safe isolation — making the circuit dead and proving it dead. PPE (insulated gloves, face protection) is the backup in case something goes wrong.
That said, there are situations where PPE is essential and cannot be avoided. Working near energised equipment (even if the specific circuit being worked on is isolated), carrying out live testing, responding to electrical faults, and working in environments where other hazards are present (construction sites, industrial premises) all require appropriate PPE. The risk assessment for each job should identify exactly which PPE is required.